Product ID:00405 SILICONE LUBE, LUBRICANTS RUST (SUPDAT)
MSDS Date:02/01/1992
FSC:9150
NIIN:00N074250
MSDS Number: CCRKD

SHERWIN WILLIAMS CO

6830 COCHRAN RD
SOLON, OH 44139
US

Emergency Phone: 216-292-7400

Info Phone: 800-777-2966

Cage: 54626

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 16%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 79.50%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

16% BY WEIGHT EXCLUDING

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS.

RTECS: 9999999ZZ

LAB ANIMALS EXPOSED TO HIGH LEVELS OF METHYLENE

RTECS: 9999999ZZ

IS NO EVIDENCE TO DATE THAT METHYLENE CHLORIDE

RTECS: 9999999ZZ

LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY,

RTECS: 9999999ZZ

HAVE ASSOCIATED RPTD & PRLNGD OVEREXPOSURE TO

RTECS: 9999999ZZ

KEEP AREA VENTD.

RTECS: 9999999ZZ

HEATERS. TURN OFF STOVES, ELEC TOOLS & APPLIANCES &

RTECS: 9999999ZZ

APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER

RTECS: 9999999ZZ

ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES,

RTECS: 9999999ZZ

BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF THE

RTECS: 9999999ZZ

HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID

RTECS: 9999999ZZ

WASH HANDS AFTER USING. THIS COATING MAY CONTAIN

RTECS: 9999999ZZ

PRESENT AT HAZ LEVELS ONLY DURING SANDING OR

RTECS: 9999999ZZ

THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH

RTECS: 9999999ZZ

5 MG/M3 (RESPIRABLE FRACTION).

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A
SIMILAR EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUS TAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . IRRIT OF EYES, SKIN
& (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONOGRAPHS,
SUPP, VOL 7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ:RESP SYS. MAY CAUSE NERVOUS SYS
DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. OVEREXP TO
METHYLENE CHLORIDE CAN RAISE THE LEVEL OF CARBON MONOXIDE IN BLOOD.
HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS OF EXCESS
EXPOS TO VAPS OR SPRAY MISTS. REDNESS & ITCHING OR BURNING
SENSATION (ING 4)
Medical Cond Aggravated by Exposure:CARDIOVASCULAR PROBLEMS MAY BE
AGGRAVATED BY OVEREXPOSURE TO METHYLENE CHLORIDE.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
FLUSH EYE S W/LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. DO
NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF WATER. SEEK MED ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP. WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG
NOZZS ARE PREF. WATER MAY BE USED TO (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAM. KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAMES. VAPORS WILL ACCUMULATE READILY &
MAY IGNITE EXPLOSIVELY. DURING USE & (ING 9)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES OR HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
THE FORM OF HCL &/OR PHOSGENE . INTENTIONAL MISUE BY DELIB
CONCENTRATING & INHALING CONTENTS CAN BE (ING 14)

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS LISTED IN INGREDIENT SECTION.
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: PREVENTATIVES & MAINTENANCE PRODUCTS 3. FIRE
FIGHT PROC: COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS
AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLAN OF CARCIN:
199 4:ANTIC TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMARY
GLAND (TUMORS).

Boiling Pt:B.P. Text:>0F,>-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HCL, PHOSGENE . BY FIRE: CARBON
DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE
CNTNR. DISPOSE OF I/A /W FED, STATE & LOCAL REGS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.